Key Collector Comics

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Avengers #66
Marvel ⋅ 1969
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Avengers #66
 
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$15
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$55
High
$160

Key Facts

First mention of Adamantium

1st appearance of Ultron-6

1st appearance of Myron MacLain, the scientist who invented Adamantium

Daredevil #196
Marvel ⋅ 1983
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Daredevil #196
 
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$1
Mid
$5
High
$18

Key Facts

First meeting and team-up of Daredevil and Wolverine

1st appearance of Lord Dark Wind, a scientist who invented the process of adamantium bonding to bone

There are 5 types of adamantium in the mainstream Marvel universe:

Proto - Captain America's shield is made of this kind

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Primary - the kind that's bonded to Wolverine's skeleton

Secondary - an adamantium/steel alloy

Beta - a version of True adamantium that changes on a molecular level when grafted to bone

Adamantine - an adamantium/gold alloy

Alpha Flight #34
Marvel ⋅ 1986
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Alpha Flight #34
 
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$1
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$2
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$5

Key Facts

Origin of Lord Dark Wind, the father of the adamantium bonding process

X-Men #25
Marvel ⋅ 1993
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X-Men #25
 
Low
$1
Mid
$2
High
$4

Key Facts

Magneto rips the Adamantium from Wolverine's skeleton revealing Logan's claws are made of bone

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