Avengers #4

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  • Captain America joins the Avengers
  • 1st cover appearance of Captain America on an official Marvel Comics cover (previously Timely, then Atlas)
  • 1st appearance of Captain America in the Silver Age
  • Death of Bucky, in a flashback
  • 1st cameo appearance of Baron Heinrich Zemo
Details
Publisher Marvel
Published March 1964
Written By Stan Lee
Illustrated By Jack Kirby