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Iron Man  (2004)

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Marvel Nov 2004 Vol 4

Iron Man #1

Iron Man #1
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1st appearance and death of Dr. Killian Aldrich, a geneticist who worked on the Extremis project
1st appearance of Dr. Maya Hansen, a scientist who worked on the Extremis project
Marvel May 2006 Vol 4

Iron Man #5

Iron Man #5
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Debut of Iron Man's 'Extremis' armor, a combination of nanotech with Stark's advanced armor enhancing the whole but more importantly, giving Tony the power to control his machinery with his thoughts
Cameo of armor still in a suitcase in issue #4

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