Ed Brubaker
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- 1st full appearance of Bucky Barnes as the Winter Soldier
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- 1st appearance of Vulcan, brother of Cyclops and Havok
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- 1st appearance of Orson Randall, the Iron Fist before Danny who focused his Chi into his firearms sometimes calling the style Gun-Fu
- 1st appearance of Bei-Ming Tian, Iron Fist of the 13th century who killed Genghis Khan
- 1st appearance of Mr. Xao, a Lightning Lord
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- 1st appearance of Wu Ao-Shi, a female Iron Fist who lived during the 16th century and mentored Orson Randall
- [August 2021 - the Shang-Chi trailer shows a character who resembles Wu Ao-Shi that appears to be named Jiang Li according to a Funko Pop]
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- 1st appearance of Bucky as Captain America
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- 1st appearance and origin of Lady Bullseye
- [September 2021 - Lady Bullseye appearing in the Hit-Monkey Hulu series]
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- An ex-super villain living a quiet life of anonymity in a Witness Protection Program reaches his breaking point
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- Reintroduction of Fu Manchu as Zheng Zu
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- 1st appearance of Niko Constantin, the only male trainee of the Wolf Spider Ops program, the male equivalent to the Black Widow program
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- 1st appearance of Nova, Sam Alexander
- 1st appearance of Kaine as the Scarlet Spider
- Death of Terrax the Tamer
- 1st team appearance of X-Terminated: Horror Show, Fiend, Deadeye, Prophet, Goodnight
- [January 2021 - the MCU maintains their intention of using Nova (Alexander & Rider) in a movie]
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