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Marvel Jan 2013 Vol 5

Avengers #3

Avengers #3
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1st full appearance of the fourth Captain Universe, Tamara Devoux
1st full appearance of Smasher
1st appearance of Nightmask, the first humanoid created by Ex Nihilo, a character adapted from Marvel's New Universe imprint (1986)
Marvel May 1998 Vol 3

Avengers #4

Avengers #4
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1st appearance of Warbird, formerly Ms. Marvel, Carol Danvers
New Avengers roster: Captain America, Hawkeye, Iron Man, Scarlet Witch, Thor, Vision, Warbid
Marvel Jul 2018 Vol 8

Avengers #5

Avengers #5
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Origin of super-powered beings on Earth, the Celestial known as the Progenitor fell to Earth, diseased and ready to die
1st full appearance and death of the Progenitor, a diseased Celestial
Marvel Oct 2010 Vol 4

Avengers #6

Avengers #6
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1st full appearance of the Next Avengers: Torunn, Henry Pym Jr., Francis Barton, James Rogers , Azari, the son of T'Challa and Storm from an alternate reality
Characters are not fully identified by name or parentage until Avengers World #9
Marvel Apr 2017 Vol 6

Avengers #6

Avengers #6
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Cover art by Alex Ross featuring Kang
Vision and a future version of the Vision engage in a conversation that involves the paradox of Theseus's ship, a sequence adapted for WandaVision on Disney+
Marvel Aug 2018 Vol 8

Avengers #6

Avengers #6
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Story arc concludes that pits the Avengers against the Dark Celestials who may have larger ties to ongoing stories past and present in the Marvel Universe
*Key Issue Status: Unknown

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